Comparison of Absorption, Fluorescence, and Polarization Spectroscopy of Atomic Rubidium

An ongoing spectroscopic investigation of atomic rubidium utilizes a two-photon, single-laser excitation process. Transitions accessible with our tunable laser include 5P1/2 (F ′ ) ← 5S1/2 (F) and 5P3/2 (F ′ ) ← 5S1/2 (F). The laser is split into a pump and probe beam to allow for Doppler-free measurements of transitions between hyperfine levels. The pump and probe beams are overlapped in a counter-propagating geometry and the laser frequency scans over a transition. Absorption, fluorescence and polarization spectroscopy techniques are applied to this basic experimental setup. The temperature of the vapor cell and the power of the pump and probe beams have been varied to explore line broadening effects and signal-to-noise of each technique. This humble setup will hopefully grow into a more robust experimental arrangement in which double resonance, two-laser excitations are used to explore hyperfine state changing collisions between rubidium atoms and noble gas atoms. Rb-noble gas collisions can transfer population between hyperfine levels, such as 5P3/2 (F ′ = 3) Collision ←− 5P3/2 (F ′ = 2), and the probe beam couples 7S1/2 (F ′′ = 2) ← 5P3/2 (F ′ = 3). Polarization spectroscopy signal depends on the rate of population transfer due to the collision as well as maintaining the orientation created by the pump laser. Fluorescence spectroscopy relies only on transfer of population due to the collision. Comparison of these techniques yields information regarding the change of the magnetic sublevels, mF , during hyperfine state changing collisions

Global Analysis of Data on the Spin-orbit-coupled A1Σ+ and b3Πu States of Cs2

We present experimentally derived potential curves and spin-orbit interaction functions for the strongly perturbed A1+ u and b3u states of the cesium dimer. The results are based on data from several sources. Laser-induced fluorescence Fourier transform spectroscopy (LIF FTS) was used some time ago in the Laboratoire Aim´e Cotton primarily to study the X1+ g state. More recent work at Tsinghua University provides information from moderate resolution spectroscopy on the lowest levels of the b3± 0u states as well as additional high resolution data. From Innsbruck University, we have precision data obtained with cold Cs2 molecules. Recent data from Temple University was obtained using the optical-optical double resonance polarization spectroscopy technique, and finally, a group at the University of Latvia has added additional LIF FTS data. In the Hamiltonian matrix, we have used analytic potentials (the Expanded Morse Oscillator form) with both finite-difference (FD) coupled-channels and discrete variable representation (DVR) calculations of the term values. Fitted diagonal and off-diagonal spin-orbit functions are obtained and compared with ab initio results from Temple and Moscow State universities

Experimental Studies of NaCs

We present experimental studies of excited electronic states of the NaCs molecule that are currently underway in our laboratory. The optical-optical double resonance method is used to obtain Doppler-free excitation spectra for several excited states. These data are being used to obtain RydbergKlein-Rees (RKR) or Inverse Perturbation Approach (IPA) potential curves for these states. We are also trying to map the bound portion of the 1(a) 3Σ + potential using resolved laser-induced fluorescence and Fourier transform spectroscopy to record transitions into the shallow well. Bound-free spectra from single ro-vibrational levels of electronically excited states to the repulsive wall of the 1(a) 3Σ + state are also being recorded. Using the previously determined excited state potentials, we can fit the repulsive wall of the 1(a) 3Σ + state to reproduce the experimental spectra using LeRoy’s BCONT program. A slightly modified version of BCONT will also be used to fit the relative transition dipole moments, µe(R), as a function of internuclear separation R, for the various bound-free electronic transitions

Vibrational State Resolved Lifetimes of the Na2 21Σ+u Double Well State

Lifetimes of individual Na2 ro-vibrational levels of the 21Σ + u double well-state have been measured using a delayed photoionization technique. Ground state Na2 produced in a molecular beam is excited resonantly by the doubled output of a pulsed dye laser in the range 333 – 357 nm and then ionized by a 532 nm photon from a time-delayed Nd:YAG laser. By appropriate excitation laser tuning and systematic variation of the probe laser delay, ro-vibrational level resolved lifetimes are obtained for v=25- 49. The double well state lifetime values are found to decrease from about 50 ns at v=25 to about 40 ns near the barrier at around v=33 and then to increase back to about 50 ns at the highest observed level of v= 49. We have also performed lifetime calculations using the Leve8 and Bcont programs by Leroy1 , the latter in a version modified by Brett McGeehan. We find that including only bound-bound transitions, the theoretical lifetime values are too large by a factor of up to 2. Inclusion of pertinent bound-free transitions improves the agreement noticeably. 1 R. J. Le Roy, LEVEL 8.0: A Computer Program for Solving the Radial Schr¨odinger Equation for Bound and Quasibound Levels, University of Waterloo Chemical Physics Research Report CP-663 (2007); see http://leroy.uwaterloo.ca/programs/.

Experimental Studies of the NaCs 53Π0 and a3Σ+ States

We report high resolution measurements of 372 NaCs 53Π0(v, J) ro-vibrational level energies in the range 0 ≤ v ≤ 22. The data have been used to construct NaCs 53Π0 potential energy curves using the Rydberg–Klein-Rees and inverted perturbation approximation methods. Bound-free 53Π0(v, J) → 1(a)3Σ+ emission has also been measured, and is used to determine the repulsive wall of the 1(a)3Σ+ state and the 53Π0 → 1(a)3Σ+ relative transition dipole moment function. Hyperfine structure in the 53Π0 state has not been observed in this experiment. This null result is explained using a simple vector coupling model

Effects of the large gluon polarization on xg1d(x)xg_1^d(x) and J/ψ\psi productions at polarized ep and pp collisions

The recent SMC data of $xg_1^d(x)$ are reproduced with the large polarized gluons. To study further the polarized gluon distribution in a proton, we calculate the spin--dependent differential cross section for J/$\psi$ leptoproductions and the two--spin asymmetry for J/$\psi$ hadroproductions. Its experimental implication is discussed.Comment: LaTeX file, 10 pages+6 figures available upon request, KOBE-FHD-93-0

Are we talking about the same structure?: A unified approach to hypertext links, xml, rdf and zigzag

There are many different hypertext systems and paradigms, each with their apparent advantages. However the distinctions are perhaps not as significant as they seem. If we can reduce the core linking functionality to some common structure, which allows us to consider hypertext systems within a common model, we could identify what, if anything, distinguishes hypertext systems from each other. This paper offers such a common structure, showing the conceptual similarities between each of these systems and paradigms

The effect of dewatering on the combustion behaviour of Loy Yang coal in a drop tube furnace

The Mechanical Thermal Expression (MTE) process is an efficient means of removing water from low-rank coal, however the effect of dewatering on the combustion properties of lignite is largely unknown. This work examines the burnout performance of both dewatered lignite and untreated lignite in a drop tube furnace. The results show that combustion of the MTE-processed lignite is approximately 20% slower under conditions relevant to pulverised-fuel flames. This is apparently due to the reduction in pore volume which occurs during coal dewatering by the MTE process.T. R. Ballantyne, P. J. Ashman and P. J. Mullinge

Collisional Transfer of Population and Orientation in NaK

We report current work to study transfer of population and orientation in collisions of NaK molecules with argon and potassium atoms using polarization labeling (PL) and laser- induced fluorescence (LIF) spectroscopy. In the PL experiment, a circularly polarized pump laser excites a specific NaK A1Σ +(v 0=16, J 0 ) ← X1Σ +(v 00=0, J 0 ± 1) transition, creating an orientation (non-uniform MJ0 level distribution) in both levels. The linearly polarized probe laser is scanned over various 31Π(v, J 0±1) ← A1Σ +(v 0=16, J 0 ) transitions. The probe laser passes through a crossed linear polarizer before detection, and signal is recorded if the probe laser polarization has been modified by the vapor (which occurs when it comes into resonance with an oriented level). Using both spectroscopic methods, analysis of weak collisional satellite lines adjacent to these directly populated lines, as a function of argon buffer gas pressure and cell temperature, allows us to discern separately the effects collisions with argon atoms and potassium atoms have on the population and orientation of the molecule. In addition, code has been written which provides a theoretical analysis of the process, through a solution of the density matrix equations of motion for the system